Methane and n-butane oxidation with CO2 under radiofrequency plasmas of moderate pressures
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چکیده
2014 The oxidation of methane and n-butane with CO2 has been studied in 35 MHz electrical discharges, operated at variable gas flow rates (6-30 (STP) min-1), power densities (2-8 cal cm-3 s-1) and constant pressure of 20 torr. Evidence is presented that the primary step of the process is the rupture of a C-H bond and that the main route for the conversion of both methane and n-butane into CO is via the intermediate C2-hydrocarbons (C2H2, C2H4, C2H6). REVUE DE PHYSIQUE APPLIQUÉE TOME 12, SEPTEMBRE 1977, Classification Physics Abstracts 52.80 82.90
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